Demixing in binary mixtures of apolar and dipolar hard spheres

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Demixing in binary mixtures of apolar and dipolar hard spheres.

We study the demixing transition of mixtures of equal size hard spheres and dipolar hard spheres using computer simulation and integral equation theories. Calculations are carried out at constant pressure, and it is found that there is a strong correlation between the total density and the composition. The critical temperature and the critical total density are found to increase with pressure. ...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2008

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.3039512